长安大学学报(自然科学版)
JOURNAL OF CHANG'AN UNIVERSITY(NATURAL SCIENCE EDITION)
2004 Vol.24 No.5 P.123-126


C60-聚吡咯复合膜的制备及其电化学性质

Electrochemistry of C60-polypyrrole composite films

张威  刘颖  泞滨  范楼珍 

摘 要:制备了C60与聚吡咯的单层及双层复合膜.应用电化学分析法研究了它们的循环伏安性质以及石英晶体微天平性质.发现无论是单层还是双层C60-聚吡咯薄膜的电化学行为都与C60固态薄膜和聚吡咯薄膜的电化学性质不同.结果表明,多层C60-聚吡咯薄膜的电化学性质不如单层C60-聚吡咯薄膜的稳定.且单层C60-聚吡咯薄膜的电化学性质基本不受C60含量的影响.
关键词:电化学;C60-聚吡咯薄膜;循环伏安;石英晶体微天平
分类号:O646  文献标识码:A

文章编号:1671-8879(2004)05-0123-04

作者简介:张威(1963-),女,陕西西安人,长安大学讲师.
作者单位:张威(长安大学,环境科学与工程学院,陕西,西安,710054) 
     刘颖(北京师范大学,化学系,北京,100875) 
     泞滨(北京师范大学,化学系,北京,100875) 
     范楼珍(北京师范大学,化学系,北京,100875) 

参考文献:

[1]Nagase S, Kobayashi K, Akasaka T, Wakahara T.Fullerenes[A]. Kadish K M, Ruoff R S. Chemistry,Physics and Technology [C] . Wiley, New York,2000.
[2]Fleming R M, Ramirez A P, Rosseinsky M J, Murphy D W, Haddon R C, Zahurak S M. Relation of structure and superconducting transition temperatures in A3 C60 [J]. Nature, 1991, 352: 787-795.
[3]Hirsch A. Addition reaction of buckminsterfullerene (C60)[J]. Synthesis,1995, 8: 895-905.
[4]Diederich F, Thilgen C. Covalent fullerene chemistry[J]. Science, 1996, 271: 317-323.
[5]Schinazi R F, Mcmillan A S, Pharr J, Sijbesma R.Electrochemistry of solutions as well as simultaneous cyclic voltammetry and piezoelectric microgravimetry of conducting films of 2-(n-alkyl)fulleropyrrolidines[J]. Electrochem. Soc. 2000, 147(7) : 2647-2652.
[6]Xie Q, Perez-Cordero E, Echegoyen L. Electrochemical detection of C6-50 and C6-70 enhanced stability of fullerenes in solution[J]. Am. Chem. Soc, 1992,114: 3978-3982.
[7]Martin N, Sanchez L, Lescas B, Perez I. C60- based electroactive organofullerenes [ J ]. Chem. Rev. ,1998, 98: 2527-2547.
[8]Liu Y, Fan L Z, Li Y F, Xiao S Q, Li Y L. Electrochemistry of the films of a novel class C60 covalently linked PPV derivative: Electrochemical quartz crystal microbalance study in acetonitrile solutions of tetra-nbutylammonium cations[J]. Appl. Poly. Sci. 2002,86:2737-2741.
[9]Reynolds J R, Skotheim T, Elsenbaumer R L.Handbook of conducting polymers, 2nd edn [M].New York:Marcel Dekker, 1997.
[10]Roncali J. Effects of substitution of the median thiophene ring on the electrodeposition and structure of poly[J]. Terthienyls, 1993,5:1456- 1464


收稿日期:2004年4月9日

出版日期:2004年9月1日